Title of article
Calculated lanthanide contractions for molecular trihalides and fully hydrated ions: The contributions from relativity and 4f-shell hybridization
Author/Authors
Clavaguéra، نويسنده , , Carine and Dognon، نويسنده , , Jean-Pierre and Pyykkِ، نويسنده , , Pekka، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2006
Pages
5
From page
8
To page
12
Abstract
The calculated lanthanide contraction in the title systems is typically 18–21 pm of which about 9–23% comes from relativistic effects. A pronounced 4f hybridization is found for LuF3 using three different relativistic methods of calculation. Large lanthanide nuclear quadrupole coupling constants are predicted for the molecular trihalides.
Journal title
Chemical Physics Letters
Serial Year
2006
Journal title
Chemical Physics Letters
Record number
1920087
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