Title of article
The branching ratio of the O(1D) + HD reaction: A dynamical study
Author/Authors
Rio، نويسنده , , Carolina M.A. and Brandمo، نويسنده , , Joمo، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2007
Pages
7
From page
268
To page
274
Abstract
The isotopic branching on the reaction of O(1D) + HD has been the subject of several theoretical and experimental studies with results ranging from 1 to 2 for the OD/OH product ratio. We present a study of the dynamics of this reaction using a double-valued potential energy surface for the ground state water molecule. Our results predict a branching ratio close to 2 for this reaction in agreement with statistical studies but in contrast with experiment. This result can be attributed to the formation and dynamics of the intermediate complex.
Journal title
Chemical Physics Letters
Serial Year
2007
Journal title
Chemical Physics Letters
Record number
1921002
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