Title of article
Electron transfer and dissociation mechanism of ferrioxalate: A time resolved optical and EXAFS study
Author/Authors
Chen، نويسنده , , Jie and Zhang، نويسنده , , Hua and Tomov، نويسنده , , Ivan V. and Ding، نويسنده , , Xunliang and Rentzepis، نويسنده , , Peter M.، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2007
Pages
6
From page
50
To page
55
Abstract
By means of ultrafast optical transient spectroscopy and EXAFS we have measured the transient spectra kinetics and Fe–O bond length of the ferrioxalate redox reaction transients. Based on Fe–O bond distances of the photoredox intermediates and quantum chemistry DFT and H–F calculations we propose a photoredox mechanism where photodissociation precedes electron transfer.
Journal title
Chemical Physics Letters
Serial Year
2007
Journal title
Chemical Physics Letters
Record number
1921459
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