• Title of article

    Experimental and theoretical investigation of new hypervalent molecules LinF (n = 2–4)

  • Author/Authors

    Veli?kovi?، نويسنده , , Suzana R. and Koteski، نويسنده , , Vasil J. and Belo?evi? ?avor، نويسنده , , Jelena N. and Djordjevi?، نويسنده , , Vesna R. and Cveti?anin، نويسنده , , Jelena M. and Djustebek، نويسنده , , Jasmina B. and Veljkovi?، نويسنده , , Miomir V. and Ne?kovi?، نويسنده , , Olivera M. Mitrasinovic، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2007
  • Pages
    5
  • From page
    151
  • To page
    155
  • Abstract
    Hypervalent molecules of Li3F and Li4F were detected experimentally for the first time. Ionization energies determined by the thermal ionization mass spectrometry were 3.8 ± 0.2 eV for Li2F, 4.0 ± 0.2 eV for Li3F and 3.9 ± 0.2 eV for Li4F. The ionization energies obtained by ab initio calculations support the experimental findings. The lowest energy structures of the LinF (n = 2–4) molecules and their cations were also predicted.
  • Journal title
    Chemical Physics Letters
  • Serial Year
    2007
  • Journal title
    Chemical Physics Letters
  • Record number

    1922995