• Title of article

    Beyond holo/hemidirectionality in Pb(II) complexes: Can the valence lone pair be bisdirected?

  • Author/Authors

    Severen، نويسنده , , M.-C. van and Piquemal، نويسنده , , J.-P. and Parisel، نويسنده , , O.، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2009
  • Pages
    3
  • From page
    17
  • To page
    19
  • Abstract
    In this contribution, we investigate, by means of Density Functional Theory computations coupled to the analysis of the Electron Localisation Function (ELF), a new possible topology of the Pb2+ valence lone pair. The possibility of bisdirectionality is uncovered for the first time and reveals another character of lead complexes beyond holo/hemidirectionality.
  • Journal title
    Chemical Physics Letters
  • Serial Year
    2009
  • Journal title
    Chemical Physics Letters
  • Record number

    1927209