• Title of article

    Relaxation compensated and intensity recovered dynamics of cross polarization in the frame of reciprocity relation

  • Author/Authors

    Shu، نويسنده , , Wenfang and Zhang، نويسنده , , Shanmin، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2011
  • Pages
    3
  • From page
    424
  • To page
    426
  • Abstract
    Through combing the scheme of TORQUE (by Tekely et al.) with cross depolarization (CDP), we derived a relaxation compensated and intensity recovered Hartmann–Hahn CP dynamics in the frame of reciprocity relation. As a result, the CP dynamics of TORQUE (CPT1ρQ(t)) emerges from the T1ρ damped dynamics and upon normalization of the intensities by the reciprocity relation, it is perfectly symmetric with respect to the CDP(t). Along with an enhancement factor of CP defined as η(t) = [ 1 - CDP ( t ) ] ( γ I / γ S ) and a scaling factor between two peak intensities, λ ( t ′ ) = PI CP ( t ′ ) /PIT1ρQ(t′), this method provides a convenient, robust, and quantitative measure of CP spectra.
  • Journal title
    Chemical Physics Letters
  • Serial Year
    2011
  • Journal title
    Chemical Physics Letters
  • Record number

    1931721