• Title of article

    How often is the minimum polarizability principle violated?

  • Author/Authors

    Blair، نويسنده , , Shamus A. and Thakkar، نويسنده , , Ajit J.، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2013
  • Pages
    4
  • From page
    346
  • To page
    349
  • Abstract
    The minimum polarizability principle states that the polarizability is minimized as an electronic system evolves towards a stable state. This principle implies that the polarizability of a stable molecule at its equilibrium structure should be less than the sum of the polarizabilities of its constituent atoms. Careful scrutiny of 2386 experimental and theoretical polarizabilities reveals 86 violations and suggests that the minimum polarizability principle is violated approximately two to three per cent of the time.
  • Journal title
    Chemical Physics Letters
  • Serial Year
    2013
  • Journal title
    Chemical Physics Letters
  • Record number

    1934286