Title of article
19F and 199Hg NMR of trimeric perfluoro-ortho-phenylenemercury
Author/Authors
Taylor، نويسنده , , R.E. and Gabbaï، نويسنده , , François P.، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2007
Pages
5
From page
28
To page
32
Abstract
19F and 199Hg high-resolution solution NMR spectra were acquired for cyclic trimeric perfluoro-ortho-phenylenemercury. Even with the high superconducting magnetic fields currently available, the 19F spectrum was not interpretable with a simple first-order analysis. Spectroscopic parameters for chemical shift and scalar coupling interactions in the NMR spectra were extracted from four- and five-spin simulations. Differential line widths in the 19F spectrum result from scalar coupling to the 199Hg.
Keywords
Strong scalar coupling , NMR , 199Hg NMR , 19F NMR , Lewis acid , mercury , Trimeric perfluoro-ortho-phenylenemercury
Journal title
Journal of Molecular Structure
Serial Year
2007
Journal title
Journal of Molecular Structure
Record number
1964033
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