Title of article
Structural studies on acetophenone- and benzophenone-derived thiosemicarbazones and their zinc(II) complexes
Author/Authors
Ferraz، نويسنده , , Karina S.O. and Silva، نويسنده , , Nayane F. and Da Silva، نويسنده , , Jeferson G. and Speziali، نويسنده , , Nivaldo L. and Mendes، نويسنده , , Isolda C. and Beraldo، نويسنده , , Heloisa، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2012
Pages
6
From page
102
To page
107
Abstract
In the present work N(3)-meta-chlorophenyl-(HAc3mCl, 1) and N(3)-meta-fluorphenyl-(HAc3mF, 2) acetophenone thiosemicarbazone, and N(3)-meta-chlorophenyl-(HBz3mCl, 3) and N(3)-meta-fluorphenyl-(HBz3mF, 4) benzophenone thiosemicarbazone were obtained, as well as their zinc(II) complexes [Zn(Ac3mCl)2] (5), [Zn(Ac3mF)2] (6), [Zn(Bz3mCl)2] (7) and [Zn(Bz3mF)2] (8). Upon re-crystallization in DMSO:acetone conversion of 8 into [Zn(Bz3mF)2]·(DMSO) (8a) occurred. The crystal structures of 2, 5 and 8a were determined.
Keywords
Zinc(II) complexes , thiosemicarbazones , crystal structures
Journal title
Journal of Molecular Structure
Serial Year
2012
Journal title
Journal of Molecular Structure
Record number
1970864
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