Title of article
Compensation and cooperative effects in H-bond thermodynamics of hydroperoxides
Author/Authors
Remizov، نويسنده , , A.B. and Skochilov، نويسنده , , R.A.، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2012
Pages
4
From page
35
To page
38
Abstract
Self-association of cumyl (CUH), tertiary butyl and 3-phenylmethyl hydroperoxides in various solvents and hetero-association of CUH with acetone and acetophenone in n-decane solutions were studied by FTIR spectroscopy. The obtained results were analyzed in combination with DFT data on linear and cyclic CUH self-associates. The analysis of the complexation enthalpies and entropies revealed compensation and cooperative effects, which were for the first time observed for H-bonding of hydroperoxides.
Keywords
Hydroperoxides , Infrared spectra , Compensation effect , Cooperative effect , Hydrogen bond
Journal title
Journal of Molecular Structure
Serial Year
2012
Journal title
Journal of Molecular Structure
Record number
1971418
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