• Title of article

    On molecular-based equations of state: rigor versus speculations

  • Author/Authors

    Nezbeda، نويسنده , , Ivo، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2001
  • Pages
    13
  • From page
    3
  • To page
    15
  • Abstract
    A general scheme for developing any semi-empirical molecular-based equation of state is formulated along with several rules which reflect the essentials of physics of fluids and which should be observed. Approximations and simplifications used in the implementation of the scheme are analyzed in the light of these rules and examples showing superiority of molecular-based considerations over purely intuitive or empirical ones are presented.
  • Keywords
    Molecular-based equations , Statistical mechanics , Perturbation expansion
  • Journal title
    Fluid Phase Equilibria
  • Serial Year
    2001
  • Journal title
    Fluid Phase Equilibria
  • Record number

    1983249