Phase equilibria and excess properties for binary systems in reactive distillation processes. Part II. Ethyl acetate synthesis

In this investigation isothermal vapor–liquid equilibrium data (VLE) and excess enthalpy (HE) data were measured for the binary systems required for the design of reactive distillation processes for the ethyl acetate production. The isothermal P–x data was measured with a static apparatus, the heat of mixing measurements were performed with a commercial isothermal flow calorimeter. To the experimental data from this work and mixture data from other authors temperature dependent UNIQUAC parameters were fitted.