• Title of article

    Excess molar enthalpies and excess molar volumes of methyl methacrylate + benzene, + toluene, + p-xylene, + cyclohexane and + aliphatic diethers (diethyl, diisopropyl and dibutyl)

  • Author/Authors

    George، نويسنده , , John and Sastry، نويسنده , , N.V and Prasad، نويسنده , , D.H.L، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2003
  • Pages
    13
  • From page
    39
  • To page
    51
  • Abstract
    Experimental values of excess molar enthalpies (HmE) at T=298.15 K and excess molar volumes (VmE) at T=298.15–318.15 K for binary liquid mixtures of methyl methacrylate (MMA) + benzene, + toluene, + p-xylene, + cyclohexane and + diethers (diethyl, diisopropyl and dibutyl) are reported. The qualitative analysis of both the excess molar functions was done taking in to consideration the molecular size of ethers and the nature of the hydrocarbon. The results show that besides the weakening of dipolar forces among ester molecules, specific but weak interactions of n⋯π and dipole–dipole types are significant in these mixtures (with an exception in MMA+cyclohexane).
  • Keywords
    Density , Enthalpy , Ethers + hydrocarbon mixtures , excess molar volume
  • Journal title
    Fluid Phase Equilibria
  • Serial Year
    2003
  • Journal title
    Fluid Phase Equilibria
  • Record number

    2033758