Title of article
Thermal reactions between alkanes and H2S or thiols at high pressure
Author/Authors
Nguyen، نويسنده , , V.P. and Burklé-Vitzthum، نويسنده , , V. and Marquaire، نويسنده , , P.M. and Michels، نويسنده , , R.، نويسنده ,
Pages
13
From page
307
To page
319
Abstract
Confined pyrolysis in gold cells of n-octane/H2S mixtures was carried out between 310 °C and 350 °C under 700 bar for durations of 3–13 days. The main products were thiophene, alkylthiophenes, octanethiols and alkyl-thiacycloalkanes and their quantities were measured. Some experiments were also carried out at 350 °C on n-octane/thiol mixtures and the results were compared to those obtained with H2S. The formation pathways of the main products, which are similar for both reactant mixtures, are proposed.
Keywords
n-Octane , Organic sulfur compounds , Thiophenes , Pyrolysis , H2S , thiols , high pressure , alkanes
Journal title
Astroparticle Physics
Record number
2036137
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