Title of article
New organic metals: BEDO-TTF bromomercurates
Author/Authors
Zhilyaeva، نويسنده , , E.I. and Lyubovskaya، نويسنده , , R.N. and Konovalikhin، نويسنده , , S.V. and Dyachenko، نويسنده , , O.N. and Lyubovskii، نويسنده , , R.B.، نويسنده ,
Issue Information
دوماهنامه با شماره پیاپی سال 1998
Pages
6
From page
35
To page
40
Abstract
Electrochemical oxidation of BEDO-TTF (bis(ethylenedioxy)tetrathiafulvalene) in the presence of Bu4NHgBr3 or Bu4NHgBr3 + Bu4NBr as a supporting electrolyte in 1,2-dichloroethane (DCE) allows the isolation of (BEDO-TTF)2HgBr3, (BEDO-TTF)5Hg1.9Br6.8, (BEDO-TTF)9(HgBr4)2·5DCE or (BEDO-TTF)C10.5·1.5H2O radical cation salts depending on conditions of electrochemical synthesis. Conditions for the synthesis, crystal structures and conductivity of the resulting BEDO-TTF bromomercurates are discussed.
Keywords
Bis(ethylenedioxy)tetrathiafulvalene , Electrocrystallization , Organic metals , Bromomercurate anions , crystal structures
Journal title
Synthetic Metals
Serial Year
1998
Journal title
Synthetic Metals
Record number
2071779
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