Title of article
Nonlinear optical properties of chiral thiolates
Author/Authors
Sylla، نويسنده , , M. and Giffard، نويسنده , , M. and Boucher، نويسنده , , V. and Illien، نويسنده , , B. and Mercier، نويسنده , , N. and Nguyen Phu، نويسنده , , X.، نويسنده ,
Issue Information
دوماهنامه با شماره پیاپی سال 1999
Pages
2
From page
1548
To page
1549
Abstract
Aromatic thiolate anions ArS− are expected from a semi-empirical calculation with PM3 parametrisation of the MNDO Hamiltonian, to possess higher intrinsic polarizabilities than the parent neutral thiols ArSH. Noncentrosymmetric thiolate salts have been synthesized by the reaction of ArSH with chiral amines and investigated for their second-order (through frequency doubling) and third-order (through degenerate four-wave mixing technique) nonlinear optical properties.
Keywords
Semi-empirical models , coupling reactions , nonlinear optical models and methods
Journal title
Synthetic Metals
Serial Year
1999
Journal title
Synthetic Metals
Record number
2072748
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