Title of article
Pressure-induced insulating state in (BO)2Cl(H2O)x
Author/Authors
Hanazato، نويسنده , , S. and Mori، نويسنده , , T. and Mori، نويسنده , , H. and Tanaka، نويسنده , , S.، نويسنده ,
Issue Information
دوماهنامه با شماره پیاپی سال 1999
Pages
2
From page
1770
To page
1771
Abstract
The title compound is a θ-phase salt which exhibits metallic conductivity down to low temperatures. Since the universal phase diagram of θ-phase predicts the existence of an insulating phase under pressure, conductivity under high pressure has been investigated. The metallic temperature dependence is switched to flat dependence above 4 kbar, and semiconducting dependence appears above 10 kbar.
Keywords
Metal-insulator phase transitions , Organic conductors based on radical cation and/or anion salts , X-ray absorption spectroscopy
Journal title
Synthetic Metals
Serial Year
1999
Journal title
Synthetic Metals
Record number
2072859
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