• Title of article

    Experimental and theoretical studies of the anisotropical complex dielectric constant of highly stretch-oriented poly(p-phenylene-vinylene)

  • Author/Authors

    Comoretto، نويسنده , , D and Dellepiane، نويسنده , , G and Marabelli، نويسنده , , F and Tognini، نويسنده , , P and Stella، نويسنده , , A and Cornil، نويسنده , , J and dos Santos، نويسنده , , D.A. and Brédas، نويسنده , , J.L and Moses، نويسنده , , D، نويسنده ,

  • Issue Information
    دوماهنامه با شماره پیاپی سال 2001
  • Pages
    4
  • From page
    107
  • To page
    110
  • Abstract
    We report on the determination of the anisotropical complex optical constants of highly stretch-oriented poly(p-phenylene-vinylene) (PPV) from Kramers–Kronig transformation of near-normal incidence absolute reflectivity and inversion of reflectance and transmittance measurements. These data are discussed and compared with those obtained from quantum chemical calculations extended to include the electronic correlation in an 11-ring PPV oligomer. On the basis of this comparison a new assignment of the optical transitions in PPV is proposed.
  • Keywords
    Poly(p-phenylenevinylene) , Complex refractive index
  • Journal title
    Synthetic Metals
  • Serial Year
    2001
  • Journal title
    Synthetic Metals
  • Record number

    2073903