CORRELATION BETWEEN IONIC-COVALENT PARAMETERS AND INFRARED SPECTROSCOPIC DATA IN II-III TRANSITION METAL SPINEL-TYPE OXIDES

The infrared reflection spectra of II-III transition metal spinel-type oxides AB2O4 (A = Mg, Mn, Fe, Co, Ni, Cu and Zn; B = Al, Cr, Fe, Co, Ga, Rh) are presented. The spectra are discussed in terms of cation distribution and ionicity of these compounds. The (TO-LO)1 splitting of the two high energy bands supplies a criterion for the ionic character. A linear relationship between the ionic-covalent parameter (ICP) of the octahedral trivalent cation and the (TO-LO)1 splitting is observed for normal spinels, and another one between the parameter SSp = ΣICPtetra + ΣICPocta and the (TO-LO)1 splitting is observed for inverse and partially inverse spinels. (ICP is a new parameter related to acid strength, taking into account the ionic-covalent character of the bond [Portier et al., J. Alloys Comp. 209, 285–289 (1994)]. This study shows that the ionicity of AB2O4 spinels is mainly determined by ICP of the trivalent cation, the nature and coordination of the divalent cation, and the existence of a Jahn-Teller effect. Assignments of high-energy bands are proposed. © 1997 Elsevier Science Ltd