Title of article
New palladium phosphate complexes: K2PdP2O7 and K3.5Pd2.25(P2O7)2 synthesis, single crystal structure and conductivity
Author/Authors
A. El Maadi، نويسنده , , A and Bennazha، نويسنده , , J and Réau، نويسنده , , J.M and Boukhari، نويسنده , , A and Holt، نويسنده , , E.M، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
10
From page
865
To page
874
Abstract
Two new diphosphate complexes containing potassium and palladium, K2PdP2O7 and K3.5Pd2.25(P2O7)2, have been synthesized and characterized by single crystal X-ray diffraction. K2PdP2O7 exists with layers formed of linked PdP2O7 polyhedra, between which are found the potassium ions. K3.5Pd2.25(P2O7)2 with a Pd/P2O7 ratio of 1.125:1 crystallizes with tunnels of various sizes in which are found the potassium ions. Conductivity measurements reveal the material to be conducting.
Keywords
A. Ceramics , D. Crystal structure , D. Electrical properties , C. X-ray diffraction
Journal title
Materials Research Bulletin
Serial Year
2003
Journal title
Materials Research Bulletin
Record number
2096261
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