Title of article
Syntheses of the new compounds NaBi6O9X (X = Br, I) and the mixed systems Na0.77(3)K0.23(3)Bi6O9I, Rb0.91(3)K0.05(1)Na0.04(2)Bi6O9Br and Rb0.89(4)K0.05(1)Na0.06(3)Bi6O9I
Author/Authors
Keller، نويسنده , , Egbert and Krنmer، نويسنده , , Volker and Meyer، نويسنده , , Clemens A.، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2007
Pages
4
From page
1391
To page
1394
Abstract
The new compounds NaBi6O9X (X = Br, I) were synthesized. Attempts to synthesize the analogous RbBi6O9X (X = Br, I) compounds yielded mixed systems with about 10% of the Rb atoms replaced by Na and K atoms. Another mixed system, Na0.77(3)K0.23(3)Bi6O9I, was obtained incidentally. The corresponding ABi6O9X compounds with X = Cl or A = Cs could not be obtained. The influence of A and X on the size of the ABi6O9X unit cell is discussed.
Keywords
A. Oxides , A. halides , B. Chemical synthesis , C. X-ray diffraction
Journal title
Materials Research Bulletin
Serial Year
2007
Journal title
Materials Research Bulletin
Record number
2098350
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