Title of article
Catalyzed Oxidation of Cyclohexene and Cyclooctene with First Row Transition etallophthalocyanines
Author/Authors
-، - نويسنده Department of Chemistry, Shahid Beheshti University, P.O. Box 1983963113 Tehran, I.R. IRAN Piroozmand, Mahtab , -، - نويسنده Department of Chemistry, Shahid Beheshti University, P.O. Box 1983963113 Tehran, I.R. IRAN Safari, Nasser , -، - نويسنده Department of Chemistry, Shahid Beheshti University, P.O. Box 1983963113 Tehran, I.R. IRAN Samadi, Abbas Ali
Issue Information
فصلنامه با شماره پیاپی 40 سال 2006
Pages
5
From page
85
To page
89
Abstract
-
Abstract
First row transition metal complexes of phthalocyanine are employed as catalysts for the oxidation of cyclohexene and cyclooctene using iodosylbenzene and pentafluoroiodosyl benzene. The catalysis was performed in dichloromethane: methanol:water (80:18:2) solvent mixture. The products of the catalysis for cyclohexene are epoxycyclohexane, 2-cyclohexene-1-ol and 2-cyclohexene-1-one whereas for cyclooctene it is specifically cyclooctene oxide. For cyclohexene oxidation epoxide yield and selectivity is in the order of MnII > FeIII > FeII > CoII > CrIII > NiII > CuII , while for 2-cyclohexene-1-one production the ability of the catalysts are in the order of NiII > CoII > CuII > CrIII > FeIII > FeII > MnII .
Journal title
Iranian Journal of Chemistry and Chemical Engineering (IJCCE)
Serial Year
2006
Journal title
Iranian Journal of Chemistry and Chemical Engineering (IJCCE)
Record number
2149516
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