Structure and properties of highly oriented polyoxymethylene produced by hot stretching

Highly oriented self-reinforced polyoxymethylene (POM) was successfully fabricated through solid phase hot stretching technology. The tensile strength and modulus increased with draw ratio, which reached 900 MPa and 12 GPa, respectively at a high draw ratio of 900% without remarkable drop of the elongation at break. The structure and morphology of the drawn products were studied and the mechanical structure model of microfibril of POM was established. Raman spectral exhibited a low-frequency shift, which indicated two types of molecular chains with different response to the stress. During drawing, the spherulitic structure of POM was broken up and the mat texture crystals were formed. With the increase of draw ratio, the melting peak moved to high temperature and an additional shoulder peak ascribed to melting of highly chain-extended and oriented crystalline blocks was observed. X-ray diffraction showed that the crystallinity and orientation factor increased, while the grain size perpendicular to (1 0 0) crystal plane of POM decreased by drawing. The α relaxation peak corresponding to the glass transition temperature of POM (Tg) moved to high temperature with draw ratio. The section morphology of drawn POM exhibited a fibrillar structure which contributed to the significantly high tensile strength and modulus of the product.