Hierarchical microstructure of explosive joints: Example of titanium to steel cladding

The microstructure of explosive cladding joints formed among parallel Ti and steel plates was examined by electron microscopy. The bonding interface and the bulk materials around it form pronounced hierarchical microstructures. This hierarchy is characterized by the following features: at the mesoscopic scale of the hierarchy a wavy course of the interface characterizes the interface zone. This microstructure level is formed by heavy plastic shear waves (wavelength ≈ 0.5 mm) which expand within the two metal plates during the explosion parallel to the bonding interface. At the micro-scale range, intermetallic inclusions (size ≈ 100–200 μm) are formed just behind the wave crests on the steel side as a result of partial melting. Electron diffraction revealed FeTi and metastable Fe9.64Ti0.36. Most of the observed phases do not appear in the equilibrium Fe–Ti phase diagram. These intermetallic inclusions are often accompanied by micro-cracks of similar dimension. At the smallest hierarchy level we observe a reaction layer of about 100–300 nm thickness consisting of nano-sized grains formed along the entire bonding interface. Within that complex hierarchical micro- and nanostructure, the mesoscopic regime, more precisely the type and brittleness of the intermetallic zones, seems to play the dominant role for the mechanical behavior of the entire compound.