Title of article
Study of intermolecular interactions in binary mixtures of 2′-chloro-4-methoxy-3-nitro benzil in various solvents and at different concentrations by the measurement of acoustic properties
Author/Authors
Nithya، نويسنده , , G. and Thanuja، نويسنده , , B. and Kanagam، نويسنده , , Charles C.، نويسنده ,
Issue Information
فصلنامه با شماره پیاپی سال 2013
Pages
6
From page
265
To page
270
Abstract
Density (ρ), ultrasonic velocity (u), adiabatic compressibility (β), apparent molar volume (Ø), acoustic impedance (Z), intermolecular free length (Lf), relative association (RA) of binary mixtures of 2′-chloro-4-methoxy-3-nitro benzil (abbreviated as 2CBe) in ethanol, acetonitrile, chloroform, dioxane and benzene were measured at different concentrations at 298 K. Several useful parameters such as excess density, excess ultrasonic velocity, excess adiabatic compressibility, excess apparent molar volume, excess acoustic impedance and excess intermolecular free length have been calculated. These parameters are used to explain the nature of intermolecular interactions taking place in the binary mixture. The above study is useful in understanding the solute – solvent interactions occurring in different concentrations at room temperature.
Keywords
ultrasonic velocity , Excess parameters , Intermolecular hydrogen bonding , Density
Journal title
Ultrasonics Sonochemistry
Serial Year
2013
Journal title
Ultrasonics Sonochemistry
Record number
2190280
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