Changes in gas composition prior to a minor explosive eruption at Masaya volcano, Nicaragua

A small explosive eruption at Masaya volcano on 23 April 2001, in which a number of people were injured, was preceded by a distinct change in plume gas compositions. Open-path Fourier transform infrared spectroscopy (FTS) measurements show that the SO2/HCl molar ratio increased from 1.8 to 4.6 between April 2000 and April/May 2001. The SO2 flux decreased from 11 to 4 kg s−1 over this period. We interpret these changes to be the result of scrubbing of water-soluble magmatic gases by a rejuvenated hydrothermal system. A sequence of M 5 earthquakes with epicentres about 7 km from the volcano occurred in July 2000. These may have altered the fracture permeability close to the magmatic conduit, and caused increased magmatic–hydrothermal interaction, leading eventually to the phreatic explosion in 2001. Continuous FTS measurements at suitable volcanoes could provide useful information in support of eruption prediction and forecasting.