Weathering of igneous rocks during shallow burial in an upland peat environment: observations from the Bronze Age Copney Stone Circle Complex, Northern Ireland

The stone circle complex at Copney, County Tyrone is a key Bronze Age site that forms part of the Mid-Ulster stone circle complex. This site was excavated in 1995 and since then, deterioration of the archaeological stonework has been a serious problem. Deterioration is visible as splitting/fracturing of stones, the development of a bleached outer margin, surface scaling and granular disintegration, and, in some cases, complete disintegration of individual stones to sandy regolithic material. Environmental conditions at this site exacerbate the deleterious action of weathering processes, with periodic waterlogging and sub-zero temperatures during winter months. pney stones comprise two igneous lithologies: quartz porphyry and porphyritic andesite, both Lower Ordovician (470 Ma) in age. Both rock types show extensive alteration by hydrothermal processes resulting in weakened stone fabrics exploited by weathering processes during burial and subsequent exposure. Mineralogy of buried and exposed material indicates that approximately 2500 years of burial in a peat bog has produced secondary porosity comprising extensive microfracture networks and dissolution voids, which permitted further ingress of moisture and acidic waters, thus, promoting chemical alteration of mineral constituents. The occurrence of completely grussified stones and arenisation of boulder surfaces at Copney indicates that the processes of grussification are not solely restricted to deep weathering environment but can be achieved by burial in a shallow, aggressive environment over periods measured in thousands of years.