An ion microprobe study of clinopyroxenes in websteritic and megacrystic xenoliths from Hyblean Plateau (SE Sicily, Italy): constraints on HFSE/REE/Sr fractionation at mantle depth

Eleven clinopyroxenes from websteritic (Cr-diopside- and Al-diopside-bearing) and Al-augite±orthopyroxene±spinel-bearing megacrystic xenoliths occurring in alkaline volcanics of the Hyblean Plateau (SE Sicily) were analysed for rare-earth and other trace elements (Sc, Ti, V, Cr, Sr, Y, Zr) with an ion microprobe. element analysis shows that Hyblean pyroxenites are crystal/liquid segregates of basaltic magmas characterized by different composition (from tholeiitic to alkaline) and variable LILE enrichment. Megacrystic clinopyroxenes are, most probably, high-pressure liquidus phases of OIB-type alkaline basalts characterized by smooth chondrite-normalized trace-element abundance plots, except for a slight negative Sr anomaly. Clinopyroxenes from websterites crystallized from either alkaline or tholeiitic melts and later experienced metamorphic (orthopyroxene exsolution) and/or metasomatic (interaction with fluids or melts) processes which modified to variable extent their original major-and trace-element signatures. lean high-pressure alkaline basalts, compositional factors (i.e. major-element activities in the melt and clinopyroxene crystal chemical configuration) caused a significant DTi increase, mild DREE and DZr increases, and virtually no DSr variations with increasing degree of fractionation. In particular, clinopyroxene crystal chemical constraints, namely electrostatic balance and M1-site geometry, appear to play a major role in the creation of HFSE/REE and Sr/REE decoupling in clinopyroxene-bearing mantle rocks. A sharp decrease of DZr with increasing pressure is predicted from crystal chemical considerations.