Patterned surfaces via self-assembly

The self-assembly of block copolymers, homopolymers and surfactants on surfaces often leads to well-defined patterns with topologically or chemically distinct regions. Important recent developments in controlling the nature of the pattern include methods to produce patterns via passive adsorption of a solid substrate; coupling of substrate topology and polymer phase separation in order to effect control over pattern formation; and methods to `tuneʹ the surface potential of the substrate to eventually control pattern formation. The use of the polymer-patterned surface as a nanolithography mask has also been demonstrated in two very interesting systems. © 1999 Elsevier Science Ltd.