230Th in the eastern North Atlantic: the importance of water mass ventilation in the balance of230Th

The230Th distribution in the water column on a north-south transect in the eastern North Atlantic was measured using thermal ionization mass spectrometry (TIMS). Water samples at three locations (L1, 33°N 21.6°W; L2, 47.4°N 19.5W; and L3, 54.4°N 21.1°W) were filtered and the dissolved and particulate fractions were analysed for their230Th and232Th contents. In the upper water column (< 1000 m water depth), the total230Thex distribution at the three locations could be explained by a reversible scavenging model. In the deep water column, however,230Thex concentrations decrease from south to north with relatively low and constant concentrations at stations L2 and L3. The major water mass below 2000 m is North East Atlantic Deep Water (NEADW), filling the deep water column at L1. The water column at L2 and L3 is influenced by Labrador Sea Water (LSW) down to 2000 m, whereas at L3, the deep water is strongly influenced by Iceland-Scotland Overflow Water (ISOW). The anomalous distribution of230Thex in the deep water column of stations L2 and L3 could be described after a ventilation term was added to the equations of the reversible scavenging model. For L3, a ventilation time (3–12 years) was found comparable to results derived from other tracers. However, the ventilation of the deep water (>2000 m) at L2 suggested by our model (8–25 years) is probably too rapid in comparison with previous findings based on chlorofluorocarbon data. Enhanced scavenging of230Th would be an alternative explanation for the low concentration in NEADW at L2. With the scavenging-mixing model, we calculated an advective export flux of230Th of up to 50% of the production in the water column in the eastern North Atlantic. Advective loss of230Th has to be taken into account when using the230Th flux into sediments for paleoceanographic studies in ocean basins where deep water residence time is comparable to the230Th scavenging residence time.