Title of article
Aqueous-Phase Oxidation of Alcohols with Green Oxidants (Oxone and Hydrogen Peroxide) in the Presence of MgFe2 O4 Magnetic nanoparticles as an Efcient and Reusable Catalyst
Author/Authors
Ramazani Ali نويسنده , Khoobi Mehdi نويسنده Department of Medicinal Chemistry, Faculty of Pharmacy and Pharmaceutical Sciences Research Center, Tehran University of Medical Sciences, Tehran 14176, Iran , Woo Joo Sang نويسنده School of Mechanical Engineerng WCU nano research center,Yeungnam University,Gyongsan 712-749 , South KOREA , Sadri Fariba نويسنده Department of Chemistry, Payame Noor University, P.O. Box 19395-3697, Tehran, Iran , Dayyani Nahid نويسنده Department of Chemistry, University of Zanjan, P O Box 45195-313, Zanjan, Iran , Azimzadeh Asiabi Pegah نويسنده Department of Chemistry, University of Zanjan, P O Box 45195-313, Zanjan, Iran. , Taghavi Fardood Saeid نويسنده Department of Chemistry, University of Zanjan, Zanjan, Iran , Ahankar Hamideh نويسنده Department of Chemistry, Abhar Branch, Islamic Azad University, Abhar, Iran
Pages
9
From page
264
Abstract
نانوذرات مغناطيسي MgFe2O4 يك كاتاليزگر فعال، پايدار ويك كاتاليزگر قابل بازيافت براي اكسايش الكل ها است. اكسايش انواع الكل ها مورد آزمايش قرار گرفت ومحصول مربوطه با بازده بالا به دست آمد. واكنش در آب در حضور اكسون در دماي اتاق و يا هيدروژن پراكسيد در دماي 60 oC به عنوان اكسنده انجام شد ساختار و مشخصه كاتاليزگر تهيه شده با تكنيك هاي IR ، XRD ، SEM و ICP مورد بررسي قرار گرفت. همچنين كاتاليزگر بدون از دست دادن فعاليت، به آساني تا 7 بار بازيافت و بكار گرفته شد.
كلمات كليدي: كاتاليزگر نانو مغناطيس، منزيم فريت، اكسايش، الكل، اكسون، هيدروژن پراكسيد.
Abstract
Nanomagnetic MgFe2
O4
is an active, stable, and reusable catalyst for the
oxidation of alcohols. Te oxidation of various primary and secondary
alcohols has been examined and related corresponding products were
obtained in good yields. Te reactions were carried out in the presence
of water as solvent and oxone (at room temperature) or H2
O2
(at 60 ?C)
as an oxidant. Te catalyst was investigated by X-ray powder difraction,
scanning electron microscope, inductively coupled plasma and infrared
techniques. Furthermore, the catalyst could be easily recovered and reused
up to 7 runs without loss of activity.
Journal title
Astroparticle Physics
Serial Year
2016
Record number
2407736
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