Title of article
Consideration of C-H…O interaction in the heterocyclic organic-inorganic hybrid material: tri-prolinium12- phosphomolibdate heteropolyoxometalate
Author/Authors
Mirzaei, Masoud Department of Chemistry - Ferdowsi University of Mashhad, Mashhad, Iran , Salimia, Ali R Department of Chemistry - Ferdowsi University of Mashhad, Mashhad, Iran , Alizadeh, Mohammad H. Department of Chemistry - Ferdowsi University of Mashhad, Mashhad, Iran , Eshtiagh-Hosseini, Hossein Department of Chemistry - Ferdowsi University of Mashhad, Mashhad, Iran , Razavi, Hossein Department of Chemistry - Georgetown University, Washington, USA
Pages
7
From page
26
To page
32
Abstract
Crystallographic data analyses indicate that three types of prolinium cations, along with two types of hydrogen bonding, produce and stabilize the helical structure of triprolinium 12-phosphomolybdate. There are similarities between this organic-inorganic compound and peptides/proteins. The stronger “conventional” hydrogen bonds and the less common C-H…O attractions play critical roles in generating and stabilizing the DNA-like network.
Keywords
Peptide , Protein , Keggin , Hybrid , Molybdenum , Polyoxometallates , Hydrogen Bonding , Proline
Journal title
Astroparticle Physics
Serial Year
2018
Record number
2429185
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