Title of article
Economic synthesis of quinaldinium fluorochromate(VI), (QnFC), and solvent-free periodic acid oxidation of alcohols catalyzed by QnFC
Author/Authors
CANBULAT ÖZDEMİR, Melek Gazi Üniversitesi - Faculty of Science - Department of Chemistry, Turkey , ÖZGÜN, Hatice Beytiye Gazi Üniversitesi - Faculty of Science - Department of Chemistry, Turkey
From page
63
To page
69
Abstract
A 1:1:1 stoichiometric reaction between CrO3 , aqueous HF, and quinaldine affords orange crystalline quinaldinium fluorochromate(VI) (QnFC) (C10H9 NH[CrO3F]) in 99.4% isolated yield. A highly efficient, simple, chemoselective, and environmentally benign procedure for QnFC (3 mol%) catalyzed oxidation of primary and secondary alcohols to aldehydes and ketones using 1.1 equiv of H5IO6 under solvent-free conditions is described.
Keywords
Periodic acid , solvent , free , oxidation of alcohols , quinaldinium fluorochromate(VI)
Journal title
Turkish Journal of Chemistry
Journal title
Turkish Journal of Chemistry
Record number
2533317
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