• Title of article

    [N′-(4-Dec­yl­oxy-2-oxido­benzyl­­idene)-3-hy­dr­oxy-2-naphtho­hydrazidato-κ3N,O,O′]di­methyl­tin(IV): crystal structure and Hirshfeld surface analysis

  • Author/Authors

    Mohd Rosely, Siti Nadiah Binti Department of Chemistry - University of Malaya, Malaysia , Duali Hussen, Rusnah Syahila Department of Chemistry - University of Malaya, Malaysia , Lee, See Mun Research Centre for Crystalline Materials - School of Science and Technology - Sunway University, Malaysia , Halcovitch, Nathan R. Department of Chemistry - Lancaster University, United Kingdom , Jotani, Mukesh M. Department of Physics - Bhavan's Sheth R. A. College of Science, India , Tiekink, Edward R. T. Research Centre for Crystalline Materials - School of Science and Technology - Sunway University, Malaysia

  • Pages
    15
  • From page
    1
  • To page
    15
  • Abstract
    The title diorganotin compound, [Sn(CH3)2(C28H32N2O4)], features a distorted SnC2NO2 coordination geometry almost inter­mediate between ideal trigonal–bipyramidal and square-pyramidal. The dianionic Schiff base ligand coordinates in a tridentate fashion via two alkoxide O and hydrazinyl N atoms; an intra­molecular hy­droxy-O—H⋯N(hydrazin­yl) hydrogen bond is noted. The alk­oxy chain has an all-trans conformation, and to the first approximation, the mol­ecule has local mirror symmetry relating the two Sn-bound methyl groups. Supra­molecular layers sustained by imine-C—H⋯O(hy­droxy), π–π [between dec­yloxy-substituted benzene rings with an inter-centroid separation of 3.7724 (13) Å], C—H⋯π(arene) and C—H⋯π(chelate ring) inter­actions are formed in the crystal; layers stack along the c axis with no directional inter­actions between them. The presence of C—H⋯π(chelate ring) inter­actions in the crystal is clearly evident from an analysis of the calculated Hirshfeld surface.
  • Keywords
    crystal structure , Hirshfeld surface analysis , Schiff base , organotin
  • Journal title
    Acta Crystallographica Section E: Crystallographic Communications
  • Serial Year
    2017
  • Record number

    2621343