• Title of article

    Crystal structure of tris­­(2-di­cyclo­hexyl­phosphino-2′,6′-dimeth­­oxy-1,1′-bi­phenyl-κP)-μ-oxoethenyl­­idene-triangulo-trigold(I) bis­­(tri­fluoro­methane­sulfon­yl)imide

  • Author/Authors

    Hartgerink, Colin T. Department of Chemistry and Biochemistry - Calvin University, USA , Staples, Richard J. Center for Crystallographic Research - Department of Chemistry - Michigan State University, USA , Anderson, Carolyn E. Department of Chemistry and Biochemistry - Calvin University, USA

  • Pages
    23
  • From page
    1
  • To page
    23
  • Abstract
    The title ketenyl­idene, [Au3(C2O)(C26H35O2P)3](C2F6NO4S2), was obtained upon exposure of [2-(di­cyclo­hexyl­phosphino)-2′,6′-dimeth­oxy-1,1′-biphen­yl]gold(I) bis­(tri­fluoro­methane­sulfon­yl)imide to acetic anhydride at elevated temperature. The ketenyl­idene bridge caps the tri-gold cluster. The title compound has provided crystals that upon analysis represent the first tri-gold ketenyl­idene with atomic distances indicative of bonding inter­action between the gold atoms.
  • Keywords
    crystal structure , tri-gold , ketenyl­idene
  • Journal title
    Acta Crystallographica Section E: Crystallographic Communications
  • Serial Year
    2021
  • Full Text URL
    journals.iucr.org/e/issues/2021/05/00/yz2006/yz2006.pdf
  • Record number

    2622087

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=2622087