• Title of article

    A redetermination of the structure and Hirshfeld surface analysis of poly[di­aquadi-μ-hydroxido-tetra­kis­(μ-nicotinato N-oxide)tricopper(II)]

  • Author/Authors

    Mirzaei, Masoud Department of Chemistry - Faculty of Science - Ferdowsi University of Mashhad, Iran , Bazargan, Maryam Department of Chemistry - Faculty of Science - Ferdowsi University of Mashhad, Iran , Ebtehaj, Pouria Department of Chemistry - Faculty of Science - Ferdowsi University of Mashhad, Iran , Mague, Joel T. Department of Chemistry - Tulane University, USA

  • Pages
    10
  • From page
    1
  • To page
    10
  • Abstract
    The product obtained from the reaction of pyridine-2,3-di­carb­oxy­lic acid and hydrated copper(II) chloride in hot aqueous NaOH solution was determined by low temperature X-ray diffraction to be [Cu3(C6H4NO3)4(OH)2(H2O)2]n or [Cu3(μ-OH)2(μ-nicNO)4(H2O)2]n (nicNO is pyridine-3-carboxyl­ate N-oxide), a structure obtained from room temperature data and reported previously. The present determination is improved in quality and treatment of the H atoms. A Hirshfeld surface analysis of the inter­molecular inter­actions is presented.
  • Keywords
    crystal structure , nicotinic acid N-oxide , copper , hydrogen bond
  • Journal title
    Acta Crystallographica Section E: Crystallographic Communications
  • Serial Year
    2021
  • Full Text URL
    journals.iucr.org/e/issues/2021/03/00/jq2004/jq2004.pdf
  • Record number

    2622266

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=2622266