• Title of article

    Ethyl 5-methyl-3-[11-(pyridin-2-yl)-6,11-di­hydro-6,11-ep­­oxy­dibenzo[b,e]oxepin-6-yl]isoxazole-4-carboxylate: a bicyclic acetal from the rearrangement of an anthracenyl isoxazole

  • Author/Authors

    Weaver, Matthew J. Department of Biomedical & Pharmaceutical Sciences - University of Montana, USA , Li, Chun Department of Chemistry - Ithaca College, USA , Campbell, Michael J. Department of Biomedical & Pharmaceutical Sciences - University of Montana, USA , Natale, Nicholas R. Department of Biomedical & Pharmaceutical Sciences - University of Montana, USA

  • Pages
    12
  • From page
    1
  • To page
    12
  • Abstract
    The title compound, C26H20N2O5, is a rearrangement product of an o-pyridinyl anthracenyl isoxazole ester. It features a bicyclic acetal structure, which has two extended almost co-planar ring systems, which subtend a fold angle of 102.17 (5)°. In the crystal, the mol­ecules are closely knitted together through C—H⋯N and C—H⋯O hydrogen bonds and form chains of alternating enanti­omers propagating along the c-axis direction.
  • Keywords
    crystal structure , anthracenyl isoxazole , isoxazole , ep­oxy­dibenzo[b,e]oxepin
  • Journal title
    Acta Crystallographica Section E: Crystallographic Communications
  • Serial Year
    2020
  • Full Text URL
    journals.iucr.org/e/issues/2020/12/00/hb7949/hb7949.pdf
  • Record number

    2622507

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=2622507