• Title of article

    Quaternary tryptammonium salts: N,N-di­methyl-N-n-propyl­tryptammonium (DMPT) iodide and N-allyl-N,N-di­methyl­tryptammonium (DMALT) iodide

  • Author/Authors

    Chadeayne, Andrew R. CaaMTech, LLC, USA , Pham, Duyen N. K. University of Massachusetts Dartmouth, USA , Golen, James A. University of Massachusetts Dartmouth, USA , Manke, David R. University of Massachusetts Dartmouth, USA

  • Pages
    13
  • From page
    1
  • To page
    13
  • Abstract
    The solid-state structures of two quaternary trytpammonium salts, namely, N,N-dimethyl-N-n-propyl­tryptammonium (DMPT) iodide [systematic name: 2-(1H-indol-3-yl)-N,N-dimethyl-N-propyl­aza­nium iodide], C15H23N2+·I−, and N-allyl-N,N-di­methyl­tryptammonium (DMALT) iodide, [systematic name: 2-(1H-indol-3-yl)-N,N-dimethyl-N-(prop-2-en-1-yl)aza­nium iodide], C15H21N2+·I−, are reported. Both salts possess a tri­alkyl­tryptammonium cation and an iodide anion in the asymmetric unit, which are joined together through N—H⋯I inter­actions. The DMALT structure was refined as an inversion twin, and the allyl group is disordered over two orientations with a 0.70 (4):0.30 (4) ratio.
  • Keywords
    crystal structure , hydrogen bonding , indoles , tryptamines
  • Journal title
    Acta Crystallographica Section E: Crystallographic Communications
  • Serial Year
    2020
  • Full Text URL
    journals.iucr.org/e/issues/2020/08/00/zq2255/zq2255.pdf
  • Record number

    2623332

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=2623332