Title of article
The missing crystal structure in the series of N,N′,N′′-tris(pyridinyl)benzene-1,3,5-tricarboxamides: the 2-pyridinyl derivative
Author/Authors
Senior, Levi Department of Chemistry - University of Zurich, Switzerland , Linden, Anthony Department of Chemistry - University of Zurich, Switzerland
Pages
10
From page
1
To page
10
Abstract
In the first reported crystal structure involving the potential ligand N,N′,N′′-tris(pyridin-2-yl)benzene-1,3,5-tricarboxamide, C24H18N6O3, intermolecular N—H⋯O hydrogen bonds link the molecules via their amide groups into slanted ladder-like chains, in which the uprights of the ladder are formed by the hydrogen-bonding interactions and the benzene ring cores of the molecules act as the rungs of the ladder. Only two of the three amide groups in the molecule are involved in hydrogen bonding and this influences the degree of out-of-plane twisting at each amide group, with the twist being more significant for those amide groups participating in hydrogen bonds.
Keywords
trimesic amide , benzenetricarboxamide , hydrogen-bonding , crystal structure
Journal title
Acta Crystallographica Section E: Crystallographic Communications
Serial Year
2020
Record number
2623570
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