• Title of article

    Tetra­aqua­[3-oxo-1,3-bis­­(pyridinium-2-yl)propan-1-olato]nickel(II) tribromide dihydrate

  • Author/Authors

    Westcott, Barry L. Department of Chemistry & Biochemistry - Central Connecticut State University,- USA , Crundwell,Guy Department of Chemistry & Biochemistry - Central Connecticut State University,- USA , Alicea-Velázquez, Nilda L. Department of Chemistry & Biochemistry - Central Connecticut State University,- USA

  • Pages
    8
  • From page
    1
  • To page
    8
  • Abstract
    The crystal structure of the title compound, [Ni(C13H11N2O2)(H2O)4]Br3·2H2O, contains an octa­hedral NiII atom coordinated to the enol form of 1,3-di­pyridyl­propane-1,3-dione (dppo) and four water mol­ecules. Both pyridyl rings on the ligand are protonated, forming pyridinium rings and creating an overall ligand charge of +1. The protonated nitro­gen-containing rings are involved in hydrogen-bonding inter­actions with neighoring bromide anions. There are many additional hydrogen-bonding inter­actions involving coordinated water mol­ecules on the NiII atom, bromide anions and hydration water mol­ecules.
  • Keywords
    crystal structure , di­pyridyl­propane­dione , pyridinium , nickel
  • Journal title
    Acta Crystallographica Section E: Crystallographic Communications
  • Serial Year
    2020
  • Full Text URL
    journals.iucr.org/e/issues/2020/02/00/zl2768/zl2768.pdf
  • Record number

    2624534

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=2624534