OVERVIEW OF CYCLICVOLTAMMETRIC STUDY an‎d CONDUCTIVITY OF SOME FLUORINATED b-DIKETONES CONTANING THIENYL UNITE

The cyclic voltammetric investigations of p-conjugated thienyl fluorinated b-diketones ligands, which canbe regarded as new type of widely used coordinative ligand, have been reported. The studies have beencarried out on a solution of respective ligand in acetonitrile. Trends of electrode potentials are observed inwhich the experimental part agrees with calculated one that published elsewhere [7]. The cyclic voltammetry curves present one irreversible oxidation wave. This wave is due to the oxidation potential ofthienyl unit and observed around 1.88 V. In addition, the curves have two-redox potential which is related to the fluorinated-β-diketone moieties. The formation of solid film of expected oligomers or dimmer onthe working electrode is discussed. Conductivity and electronic spectra have been reported.