Title of article
Reinforcing Mechanical, Water Absorption and Barrier Properties of Poly(Lactic Acid) Composites with Kenaf-Derived Cellulose of Thermally-Grafted Aminosilane
Author/Authors
Tee, Y. B. Universiti Putra Malaysia - Faculty of Engineering - Department of Process and Food Engineering, Malaysia , Rosnita, A. T. Universiti Putra Malaysia - Faculty of Engineering, Halal Products Research Institute - Department of Process and Food Engineering, Malaysia , Khalina, A. Universiti Putra Malaysia - Institute of Tropical Forestry and Forest Products, Malaysia , Chin, N. L. Universiti Putra Malaysia - Faculty of Engineering - Department of Process and Food Engineering, Malaysia , Roseliza, K. B. Universiti Putra Malaysia - Faculty of Engineering - Department of Process and Food Engineering, Malaysia , Khairul Faezah, M. Y. Universiti Putra Malaysia - Faculty of Engineering - Department of Process and Food Engineering, Malaysia
From page
563
To page
573
Abstract
The effects of filling poly(lactic acid) (PLA) composites with cellulose thermally-grafted with hydrolysed 3-aminopropyltriethoxysilane (APS) were investigated. Composites containing 30 wt% of kenaf-derived cellulose (C) and silane-grafted cellulose (SGC) were melt-blended into a PLA matrix before being hot-pressed into 0.3 mm sheets. The tensile strength of neat PLA was 47 MPa. With addition of C and SGC,the tensile strength was improved by 13% and 23%,respectively. The tensile modulus was approximately doubled for both of the composites. PLA/C and PLA/SGC composites remained brittle with marginally lowered elongation at break. The addition of C and SGC significantly increased the oxygen barrier of PLA with the reduction of oxygen transmission rate (OTR) of PLA at 76.6 cc/m^2/day to 42.2 cc/m^2/day and 40.3 cc/m2/day,respectively. This was due to the tortuous path created and crystallites induced by the fillers. The water vapour transmission rate (WVTR) for PLA,PLA/C and PLA/SGC was in the range of 21-23 g/m^2/ day. From the water absorption test,PLA/SGC reported slightly better water resistance as compared to PLA/C. The reinforcing results from these bio-based materials may suggest contribution towards packaging oxygen and moisture sensitive food.
Keywords
Cellulose , kenaf , mechanical barrier , poly (lactic acid) , silane coupling agent , waterabsorption
Journal title
Pertanika Journal of Tropical Agricultural Science (JTAS)
Journal title
Pertanika Journal of Tropical Agricultural Science (JTAS)
Record number
2652856
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