Title of article
Methanol Formation from Dichloromethane under Hydrothermal Conditions
Author/Authors
Yamasaki، Yuki نويسنده , , Enomoto، Heiji نويسنده , , Yamasaki، Nakamichi نويسنده , , Nakahara، Masaru نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 1999
Pages
-82
From page
83
To page
0
Abstract
CH(2)CI(2) (1 mole) mixed with NaOH (2 moles) was treated under hydrothermal conditions at 250 degreeC. The chlormated methane was completely hydrolyzed to form methanol and the formate by the Cannizzaro reaction. The reactant and products were analyzed by 1H-. 2H-, and (13)C-NMR. Solvent isotope effect on the transformation was also investigated. The hazardous and environmentally troublesome organic solvent was safely eonverted into the useful compounds.
Keywords
electrochemical impedance spectroscopy , anodic films , Aluminium
Journal title
CHEMISTRY LETTERS
Serial Year
1999
Journal title
CHEMISTRY LETTERS
Record number
27141
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