Title of article
Mild, Efficient and Highly Selective Hydrolysis of Acetonides with Antimony Trichloride
Author/Authors
Wu, Qinpei Beijing Institute of Technology - Dept of Appl Chem, China , Chen, Wei Beijing Institute of Technology - School of Life Science and Technology, China , Wang, Yuan Beijing Institute of Technology - School of Life Science and Technology, Beijing , Qu, Yunbo Beijing Institute of Technology - School of Life Science and Technology, China , Zhang, Qingshan Beijing Institute of Technology - Dept of Appl Chem, China
From page
271
To page
274
Abstract
A mild and efficient procedure for chemoselective and regioselective hydrolysis of acetonide with SbCl3 in the presence of other frequently used hydroxy protecting groups, TBDMS, TBDPS, Bz, Bn, Ac, Ts andTr, was described. The mechanism was examined and proposed.
Keywords
Hydrolysis , acetonide , antimony , protecting groups , catalysis , lewis acid
Journal title
letters in organic chemistry
Journal title
letters in organic chemistry
Record number
2718006
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