Title of article
Indium-Mediated Allylation of α ,α -Dichloroketones: The Synthesis of 1,1-Dichloro-2-organyl-pent-4-en-2-ols
Author/Authors
Peppe, Clovis Universidade Federal de Santa Maria - Departamento de Química, Brazil , Nóbrega, José A. Universidade Estadual da Paraíba - Departamento de Química, Brazil , Drehmer, Lia D. Universidade Federal de Santa Maria - Departamento de Química, Brazil , Martins, Marcos A.P. Universidade Federal de Santa Maria - Departamento de Química, Brazil
From page
597
To page
599
Abstract
The allylindium reagents obtained from metallic indium and allyl bromides, in THF, couple chemioselectively to the carbonyl group of a,a- dichloroketones to afford 1,1-dichloro-2-organyl-pent-4-en-2-ols in good to excellent yields
Keywords
Indium , allylindium , allylation , dichloroketones
Journal title
letters in organic chemistry
Journal title
letters in organic chemistry
Record number
2718058
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