• Title of article

    A Study of Thermal Activation of N-Nitrosoamides

  • Author/Authors

    Darbeau, Ron W Department of Chemistry - McNeese State University, Lake Charles, LA 70609, USA , Perez, Edson V Department of Chemistry - McNeese State University, Lake Charles, LA 70609, USA , Brantley, Martin Department of Chemistry - McNeese State University, Lake Charles, LA 70609, USA

  • Pages
    10
  • From page
    689
  • To page
    698
  • Abstract
    N-4-R-Benzyl-N-nitrosoamides were decomposed at various temperatures in selected solvents. From their decomposition rates, contributions from DH* and DS* evidently depend upon intramolecular and solvent effects consistent with an early metastable oxadiazetyl-type entity in the first and rate-determining step of nitrosoamide thermolyses as opposed to a first, slowest step to a trans-diazoester
  • Keywords
    trans-diazoester , oxadiazetyl , rate-determining step , activation parameters , thermolysis , N-nitrosoamide
  • Journal title
    letters in organic chemistry
  • Serial Year
    2006
  • Journal title
    letters in organic chemistry
  • Record number

    2718064

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=2718064