• Title of article

    A 1H NMR Study on the Electronic State of a Chloride-bridged Tetrakis(acetamidato) dirhodium Complex

  • Author/Authors

    Yamauchi، Miho نويسنده , , Takazaki، Yasuaki نويسنده , , Yang، Zhiyong نويسنده , , Kawamura، Takashi نويسنده , , Ikeda، Ryuichi نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2004
  • Pages
    -10
  • From page
    11
  • To page
    0
  • Abstract
    A temperature dependence of 1H NMR spin-lattice relaxation time in a zig-zag chain of chloride-bridged tetrakis(acetamidato) dirhodium was measured. The observed 1H relaxation was well explained by the fluctuation of the magnetic dipolar interaction between proton and paramagnetic electron spins, where each unpaired spin is coupled by the one-dimensional antiferromagnetic interaction above 35 K. The slight change of the electronic state in the Rh dimer was observed below 35 K.
  • Keywords
    Application-production research , Surface finish , Genetic-fuzzy system , Power requirement , prediction , grinding
  • Journal title
    CHEMISTRY LETTERS
  • Serial Year
    2004
  • Journal title
    CHEMISTRY LETTERS
  • Record number

    27396