Title of article
Green Protocol for the Synthesis of vicinal-Halohydrins from Oxiranes Using the [Bmim] PF6/LiX Reagent System
Author/Authors
Yadav، J. S. نويسنده , , Reddy، B. V. S. نويسنده , , Reddy، Ch. Srinivas نويسنده , , Rajasekhar، K. نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2004
Pages
-475
From page
476
To page
0
Abstract
Epoxides undergo rapid ring-opening with lithium halides in [bmim]PF6 or [bmim]BF4 ionic liquids under mild and neutral conditions to afford the corresponding vic-halohydrins in high to quantitative yields. The epoxides show enhanced reactivity in ionic liquids thereby reducing reaction times and improving the yields significantly. The recovered ionic liquid can be reused in three to four subsequent runs with consistent activity.
Keywords
Application-production research , grinding , prediction , Surface finish , Power requirement , Genetic-fuzzy system
Journal title
CHEMISTRY LETTERS
Serial Year
2004
Journal title
CHEMISTRY LETTERS
Record number
28021
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