Title of article
A Novel Au12 Supramolecule Composed of Two-, Three-, and Four-coordinated Au(I) Centers Constructed on the S3 Scaffolding
Author/Authors
Onaka، Satoru نويسنده , , Inoue، Katsuya نويسنده , , Nunokawa، Keiko نويسنده , , Sunahara، Tetsuya نويسنده , , Okazaki، Kazuya نويسنده , , Imai، Hiroyuki نويسنده , , Ozeki، Tomoji نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2004
Pages
-12
From page
13
To page
0
Abstract
A novel Au12 supramolecule (12) composed of two-, three-, and four-coordinated Au(I) centers was constructed on the S3 scaffolding (trithiocyanurate, S3C3N33-). 12 can be regarded as a tetramer of the Au3 unit, [AuP(3-CF3–C6H4)3]3(S3C3N3) by losing four P(3-CF3–C6H4)3 ligands upon tetramerization. A congener of the monomer unit [AuP(2-py)(C6H5)2]3 (S3C3N3) (2) was also synthesized; X-ray study on 2 revealed in turn a monomer structure.
Keywords
Application-production research , Genetic-fuzzy system , prediction , grinding , Surface finish , Power requirement
Journal title
CHEMISTRY LETTERS
Serial Year
2004
Journal title
CHEMISTRY LETTERS
Record number
28808
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