Title of article
Redox Behavior of New Ru–Dioxolene–Ammine Complexes and Catalytic Activity toward Electrochemical Oxidation of Alcohol under Mild Conditions
Author/Authors
Fujihara، Tetsuaki نويسنده , , Wada، Tohru نويسنده , , Tanaka، Koji نويسنده , , Hino، Takami نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2004
Pages
-1595
From page
1596
To page
0
Abstract
The new Ru–dioxolene–ammine complexes, [RuII(NH3)(sq)(trpy)](ClO4) (1, sq = 3,5-di-tert-butyl-1,2-benzosemiquinone, trpy = 2,2ʹ:6ʹ,2"-terpyridine) and [RuIII(NH3)(sq)(trpy)](ClO4)2 (2), were prepared. They have an ability to oxidize MeOH and i-PrOH catalytically under very mild conditions such as the electrolysis at 0 V (vs SCE) in CH2Cl2.
Keywords
Power requirement , grinding , Surface finish , Genetic-fuzzy system , Application-production research , prediction
Journal title
CHEMISTRY LETTERS
Serial Year
2004
Journal title
CHEMISTRY LETTERS
Record number
28950
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